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Anchoring of 4-dimethyl-amino substituted azobenzene dyes doped liquid crystals on substrates
OSCAR BALDOVINO PANTALEON
ROSARIO GUADALUPE PORRAS AGUILAR
ANTONIO SANCHEZ CASTILLO
JULIO CESAR RAMIREZ SAN JUAN
Acceso Abierto
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We study the anchoring of 4-dimethyl-amino substituted azobenzene dyes doped liquid crystals and the formation of permanent gratings in the nematic liquid cristal 5CB. The increase on the dipolar interaction due to trans-cis isomerization, and the resulting anchoring to the substrate, is not enough to explain the formation of permanent gratings as it is commonly believed. We demonstrate that a strong interaction of the acid group in the 4-dimethylamino-2´-carboxylic acid substituted azo (Methyl Red, MR) dye can occur with the solid substrate through hydrogen bonding intermolecular interaction leading to permanent gratings in methyl red doped liquid crystal cells.
Taylor & Francis Group
2008
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Baldovino Pantaleon, O., et al., (2008). Anchoring of 4-dimethyl-amino substituted azobenzene dyes doped liquid crystals on substrates, Taylor & Francis Group, Vol.488(1):1-10
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